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Q. Sodium fusion extract, obtained from aniline, on treatment with iron (II) sulphate and $H _2 SO _4$, in presence of air gives a Prussian blue precipitate. The blue colour is due to the formation of

Some Basic Concepts of Chemistry

Solution:

$\left[ Fe ( CN )_6\right]^{4-}$ is formed which forms Prussian blue with $Fe ^{3+}$
$Fe ^{3+}+\left[ Fe ( CN )_6\right]^{4-} \rightarrow \underset{\text{Prussian blue}}{Fe _4\left[ Fe ( CN )_6\right]_3}$