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Chemistry
SN2 mechanism is involved in the following substitution
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Q. $ S_N2$ mechanism is involved in the following substitution
Rajasthan PMT
Rajasthan PMT 2007
Haloalkanes and Haloarenes
A
$CH_3 - CH_2 - Cl + OH^-$
68%
B
$CH_3 - \underset{\overset{|}{C}H_3}{\overset{\underset{|}{C}l}{C}}-CH_3 + OH^-$
11%
C
$ CH_3 - \overset{\underset{|}{C}l}{C}H - CH_3 + OH^-$
12%
D
$CH_3 - CH_2 - \underset{\overset{|}{C}H_3}{\overset{\underset{|}{C}l}{C}}-CH_3 + OH^-$
9%
Solution:
$S _{ N } 2$ mechanism means bimolecular nucleophilic substitution mechanism. In this, rate of reaction is determined by concentration of two molecules. It is characteristic of $1^{\circ}$ alkyl halides.
(a) $CH_3 - \underset{1^{\circ}\text{alkyl halide}}{CH_2- Cl }+ OH^-$
(b) $\underset{3^{\circ}\text{alkyl halide}}{CH_3 - \underset{\overset{|}{C}H_3}{\overset{\underset{|}{C}l}{C}}- CH_3} + OH$
(c) $\underset{2^{\circ}\text{alkyl halide}}{CH_3 - \underset{\overset{|}{C}l}{C}H - CH_3} 6 OH^-$
(d) $CH_3 - \underset{3^{\circ}\text{alkyl halide}}{CH_2 - \underset{\overset{|}{C}H_3}{\overset{\underset{|}{C}l}{C}} - CH_3} + OH^-$