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Q. Regular use of which of the following fertilizer increases the acidity of soil?

AIEEEAIEEE 2007The p-Block Elements - Part2

Solution:

$(NH_4)_2\, SO_4$ is a salt of strong acid and weak base, on hydrolysis it ill produce $H^+$ ion. This will increase the acidity of soil.
$(NH_4)_2\,SO_4 \rightarrow 2NH^+_4 + SO^{2-}_4$
$NH^+_4 + H_2O \rightleftharpoons NH_4OH + H^+$
Hence, (4) is correct answer.