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Q. Read the passage given below and answer the question
The hydrogen-like species $Li^{2+}$ is in a spherically symmetric state $S_1$ with one radial node. Upon absorbing light the ion undergoes transition to a state $S_2$. The state $S_2$ has one radial node and its energy is equal to the ground state energy of the hydrogen atom.
The orbital angular momentum quantum number of the state $S_2$ is

Structure of Atom

Solution:

The state $S_2$ has one radial node and its energy is equal to the ground state energy of the hydrogen atom. This is possible only for $3p$ orbital.
$3p$ orbital has one radial node,
$n = 3$, $l = 1 \Rightarrow (n-l-1) = ( 3 - 1- 1) = l$
$E=E_{H}\times\frac{Z^{2}}{n^{2}}$
$E_{H}\times\frac{3^{2}}{2^{2}}=E_{H}$
Azimuthal quantum number for the state $S_2$,$l = 1$.