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Q. Read the following statements and choose the correct option.
(i) $S _{ N } 1$ reactions are carried out through formation of carbocation as an intermediate.
(ii) $S _{ N }$ 1 reactions are two step reactions in whịch step 1 is fast and irreversible.
(iii) Step 1 involves breaking of $C - Br$ bond which obtain energy through solvation of halide.
(iv) $S _{ N } 1$ reactions are two step reactions in which step 2 is slow and reversible.

Haloalkanes and Haloarenes

Solution:

In $S _{ N } 1$ reactions step $1$ is slow and reversible, and the slowest step is the rate determining step.