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Chemistry
Reaction of thionyl chloride with white phosphorus forms a compound [A], which on hydrolysis gives [B], a dibasic acid. [ A ] and [ B ] are respectively
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Q. Reaction of thionyl chloride with white phosphorus forms a compound [A], which on hydrolysis gives [B], a dibasic acid. $[ A ]$ and $[ B ]$ are respectively
JEE Main
JEE Main 2023
The p-Block Elements - Part2
A
$P _4 O _6$ and $H _3 PO _3$
0%
B
$PCl _5$ and $H _3 PO _4$
0%
C
$PCl _3$ and $H _3 PO _3$
100%
D
$POCl _3$ and $H _3 PO _4$
0%
Solution:
$P _4+8 SOCl _2 \rightarrow \underset{[A]}{4 PCl _3}+4 SO _2+2 S _2 Cl _2$
$PCl _3+3 H _2 O \rightarrow \underset{[B]}{H _3 PO _3}+3 HCl$