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Q. Ratio of times taken for two gases to diffuse equal volumes is $10/20$. If molecular weight of one gas is $49$, then the molecular weight of another gas is

UP CPMTUP CPMT 2010Kinetic Theory

Solution:

Let the times of diffusion for same volumes of two gases be $t_{1}$ and $t_{2}$ respectively. Then
$\frac{t_{2}}{t_{1}}=\sqrt{\frac{M_{2}}{M_{1}}}$ or $\frac{t_{2}^{2}}{t_{1}^{2}}=\frac{M_{2}}{M_{1}}$
$M_{2}=M_{1}\times\frac{t_{2}^{2}}{t_{1}^{2}}=49\times\left(\frac{20}{10}\right)^{2}$
$=196$