Given, $R=\{(x, y): 4 x+3 y=20\}$
Since, $R$ is a relation on $N$, therefore $x , y$ are the elements of $N$. In the given options $(a), (b)$ and $(d)$ satisfy the given relation, but in options $(a)$ and $(b)$ elements are not natural numbers.
Hence, option $(d)$ is the correct answer.