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Chemistry
Propan-1-ol can be prepared from propene by
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Q. $Propan-1-ol$ can be prepared from propene by
JIPMER
JIPMER 2015
Alcohols Phenols and Ethers
A
$H _{2} O / H _{2} SO _{4}$
15%
B
$Hg ( OAc )_{2} / H _{2} O$ followed by $NaBH _{4}$
8%
C
$B _{2} H _{6}$ followed by $H _{2} O _{2}$
73%
D
$CH _{3} CO _{2} H / H _{2} SO _{4}$
4%
Solution:
Hydroboration yields 1° alcohol from alkenes.
$\underset{\text{Propene}}{3CH_3CH = CH_2}\xrightarrow [THF]{BH_3 \, in} \underset{\text{Tripropyl borane}}{(CH_3CH_2CH_2)_3B} \xrightarrow[OH^-]{3H_2O_2} \underset{\text{Propan-1-ol}}{3CH_3CH_2CH_2OH + B(OH)_3 } $