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Q. Pick out the electrophiles from the following
$ BF_3, NH_3, Me_3C^{\oplus} , HCl $

AMUAMU 2016

Solution:

Electrophiles are electron defficient species. They may be Lewis acids (in which central atom has incomplete octet), cations or carbocations. Amongst the given species, $BF_3$ is a Lewis acid (as boron has incomplete octet) and $Me_3C^+$ is a carbocation. Thus, both acts as electrophiles.