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Q. $\text{pH}$ of $\text{0} \text{.1} \, \text{M}$ aqueous solution of weak monoprotic acid $\text{HA}$ is $\text{2} \text{.}$ Calculate osmotic pressure of this solution at $\text{27} \,{}^{\text{o}} \text{C} \text{.}$ Take solution constant $\text{R} \, \text{=} \, \text{0} \text{.082} \, \text{L} \, \text{atm/K-mol}$

NTA AbhyasNTA Abhyas 2020Solutions

Solution:

$\left[H^{+}\right]=0.1\times \propto =10^{- 2}$

$\therefore \, \propto =0.1$

$\pi= iCRT =1.1 \times 0.1 \times 0.082 \times 300=2.7 atm$