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Q. One mole of a monoatomic gas and one mole of a diatomic gas are initially in the same state. Both gases are expanded isothermally and then adiabatically, such that they acquire the same final state. Choose the correct statement.

KVPYKVPY 2018Thermodynamics

Solution:

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As, slope of an adiabatic curve = $-\gamma\left(\frac{p}{V}\right)$
Also, $\gamma_{\text{diatomic}}\left(=\frac{7}{5}\right)<\gamma_{\text{monoatomic}}\left(=\frac{5}{3}\right)$
So, adiabatic expansion will be moresteep for monoatomic gas, whereasisotherms for both gases are nearly same.As, work done = area under $p-V$ graph $\therefore $ Work done is more for diatomic gas