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Q. On reacting with neutral ferric chloride, phenol gives

J & K CETJ & K CET 2007Alcohols Phenols and Ethers

Solution:

Phenol reacts with neutral $FeCl _{3}$ solution to give violet colour complex which is soluble in water.
$6 C _{6} H _{5} OH + FeCl _{3} \rightarrow \underset{\text{violet colour complex}}{\left[ Fe \left( OC _{6} H _{5}\right)_{6}\right]^{3-}} +3 H ^{+}+3 HCl$