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Q. $O$ - $O$ bond length in $H _2 O _2$ is $X$ than the $O - O$ bond length in $F _2 O _2$. The $O - H$ bond length in $H _2 O _2$ is $Y$ than that of the $O - F$ bond in $F _2 O _2$. Choose the correct option for $\underline{X}$ and $\underline{Y}$ from those given below :

JEE MainJEE Main 2023Hydrogen

Solution:

According to bent rule more electronegative atom occupy less s-characters so bond length increases. $O - H$ bond will be short than $O - F$ bond due to small size of $H$ than $F$