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Q. $o$-Hydroxybenzaldehyde is a liquid at room temperature while $p$-hydroxybenzaldehyde is a high melting solid because of

Chemical Bonding and Molecular Structure

Solution:

$ o$-Hydroxybenzaldehyde shows intramolecular hydrogen bonding whereas $p$-hydroxybenzaldehyde has intermolecular hydrogen bonding. Thus $p$-hydroxybenzaldehyde is an aggregate of a number of molecules and therefore, it is a high melting solid.

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