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Q. Number of isomeric primary amines obtained from $ {{C}_{4}}{{H}_{11}}N $ are:

MGIMS WardhaMGIMS Wardha 2006

Solution:

Four isomeric primary amines of $ {{C}_{4}}{{H}_{11}}N $ are possible. $ C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}N{{H}_{2}} $ $ {{(C{{H}_{3}})}_{2}}CHC{{H}_{2}}N{{H}_{2}} $ $ C{{H}_{3}}-\underset{\begin{smallmatrix} | \\ C{{H}_{3}} \end{smallmatrix}}{\overset{\begin{smallmatrix} C{{H}_{3}} \\ | \end{smallmatrix}}{\mathop{C}}}\,-N{{H}_{2}} $ $ C{{H}_{3}}\overset{\begin{smallmatrix} N{{H}_{2}} \\ | \end{smallmatrix}}{\mathop{C{{H}_{2}}}}\,CHC{{H}_{3}} $