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Q. Most basic hydroxide among the following is

MHT CETMHT CET 2009

Solution:

Due to lanthanide contraction, the size of $M^{3+}$ ions $\left[i e, Lu ^{3+}, Eu ^{3+}, Yb ^{3+}\right.$ and $\left. Ce ^{3+}\right]$ decreases and thus, the basic strength of their hydroxides decreases.

The order of size of given $M^{3+}$ ions is

$Ce ^{3+}> Eu ^{3+}> Yb ^{3+}> Lu ^{3+}$

$\therefore $ The order of basic strength of hydroxides is

$\underset{\text{(most basic)}}

{{Ce ( OH )_{3}}}>\, Eu ( OH )_{3}>\, Yb ( OH )_{3}>\, Lu ( OH )_{3}$