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Q. Molecules / ions and their magnetic properties are given below.
Molecule/Ion Magnetic property
i $C _{6} H _{6}$ 1 Antiferromagnetic
ii $CrO _{2}$ 2 Ferrimagnetic
iii $MnO$ 3 Ferromagnetic
iv $Fe _{3} O _{4}$ 4 Paramagnetic
v $Fe ^{3+}$ 5 Diamagnetic
The correctly matched pairs in the above is

KEAMKEAM 2012The Solid State

Solution:

$C _{6} H _{6}$ is a diamagnetic substance, as it is weakly repelled by a magnetic field.

$CrO _{2}$ is a ferromagnetic substance, which is attracted very strongly by a magnetic field.

$MnO$ is an antiferromagnetic substance as its domains cancel out each other's magnetic moment.

$Fe _{3} O _{4}$ (magnetite) is a ferrimagnetic substance because in it the magnetic moments of the domains are aligned in parallel and anti-parallel direction in unequal number.

$Fe ^{3+}\left(3 d^{5}\right)$ is paramagnetic because of the presence of unpaired electrons.

Thus, the correct match is

$i -5, ii -3, iii -1, iv -2, v -4$