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Q. Methyl amine on reaction with $ HN{{O}_{2}} $ gives:

Rajasthan PMTRajasthan PMT 1997

Solution:

$ C{{H}_{3}}N{{H}_{2}}+2HN{{O}_{2}}\xrightarrow{{}} $ $ C{{H}_{3}}-\underset{Methyl\,nitrte}{\mathop{O-N=O}}\,+{{N}_{2}}+2{{H}_{2}}O $ $ 2C{{H}_{3}}N{{H}_{2}}+2HN{{O}_{2}}\xrightarrow{{}} $ $ \underset{Dimethyl\,\,ether}{\mathop{C{{H}_{3}}-O-C{{H}_{3}}}}\,+2{{N}_{2}}+3{{H}_{2}}O $