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Q. Match the following :
List I (Hybridisation) List II (Compound/ion)
A. $sp^3 d$ I. $[PtCl_4]^{2-}$
B $sp^3 d^2$ II. $SF_6$
C. $dsp^2$ III. $BCl_3$
D. $dsp^3$ IV. $PCl_5$
V. $ClF_3$

The correct match is

TS EAMCET 2019

Solution:

(A-IV)

image

$5 \sigma =5-$ hybrid orbital

$ = sp^{3} d -$ hybridisation

(B-II)

image

$ 6 \sigma \,=6 $ - hybrid orbital

$=s p^{3} d^{2} -$ hybridisation

(C-I)

image

$4 \sigma =4 -$ hybrid orbital }

$=d s p^{2}-$ hybridisation

(D-V)

image

$ 3 \sigma+2l p =5$ hybrid orbital

$=s p^{3} d$ or $d s p^{3} $