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Q. Match items of column I and II
Column I (Mixture of compounds) Column II (Separation Technique)
A $H _2 O /CH _2 Cl _2$ i Crystallization
B image ii Differential solvent extraction
C Kerosene/Naphthalene iii Column chromatography
D $C _6 H _{12} O _6 / NaCl$ iv Fractional Distillation

JEE MainJEE Main 2023Organic Chemistry – Some Basic Principles and Techniques

Solution:

A. $H _2 O / CH _2 Cl _2 \rightarrow$ ii, $CH _2 Cl _2> H _2 O$ (density) so they can be separated by differential solvent extraction.
image
C. Kerosene / Naphthalene $\rightarrow$ iv. Fractional distillation.
Due to different B.P. of kerosene and Naphthalene it can be separated by fractional distillation.
D. $C _6 H _{12} O _6 / NaCl \rightarrow$ i. Crystallization.
$NaCl$ (ionic compound) can be crystallized.