Q.
Match each of the compounds in column I with its characteristic reaction (s) in column II.
Column I
Column II
(A)
$CH_3CH_2CH_2CN$
(p)
Reduction with $Pd-C/H_2$
(B)
$CH_3CH_2OCOCH_3$
(q)
Reduction with $SnCl_2/HCl$
(C)
$CH_3- CH = CH - CH_2OH$
(r)
Development of foul smell
(D)
$CH_3CH_2CH_2CH_2NH_2$
(s)
Reduction with disobutyl aluminium hydride $(DIBAL-H)$
(t)
Alkaline hydrolysis
The correct option is
| Column I | Column II | ||
|---|---|---|---|
| (A) | $CH_3CH_2CH_2CN$ | (p) | Reduction with $Pd-C/H_2$ |
| (B) | $CH_3CH_2OCOCH_3$ | (q) | Reduction with $SnCl_2/HCl$ |
| (C) | $CH_3- CH = CH - CH_2OH$ | (r) | Development of foul smell |
| (D) | $CH_3CH_2CH_2CH_2NH_2$ | (s) | Reduction with disobutyl aluminium hydride $(DIBAL-H)$ |
| (t) | Alkaline hydrolysis | ||
Amines
Solution:
Correct answer is (d) $A \to (p,q,s,t); B \to (p,s,t); C \to (p); D \to (r)$