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  4. Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the figure. The correct order of their boiling point is

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Q. Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the figure. The correct order of their boiling point isChemistry Question Image

JEE AdvancedJEE Advanced 2014Hydrocarbons

Solution:

$III > II > I$
More the branching in an alkane, lesser will be the surface area, lesser will be the boiling point.