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Q. In which case, van't Hoff factor i remains unchanged?

Solutions

Solution:

remains unchanged when number of ions before and after complex ion remains constant.

Solute y Complex y
(a)$PtCl_{4}$ 5 $K_2[PtCl_6]$ 3
(b)$ZnCl_{2}$ 3 $Zn[(NH_3)_4]Cl_2$ 3