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Q. In two separate experiments equal quantities of an alkyl halide, $C_4H_9Cl$, were treated at the same temperature with equal volume of $0.1\, molar$ and $0.2\, molar$ solutions of $NaOH$ respectively. In the two experiments,$t_{1/2}$ of the two reactions were the same. The most likely structure of halide is

Haloalkanes and Haloarenes

Solution:

As it is independent of the concentration of $NaOH$. So, it undergoes via $S_N1$. So, most likely the halide is tertiary halide.