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Q. In the electrolytic refining of zinc

NTA AbhyasNTA Abhyas 2020The d-and f-Block Elements

Solution:

In the electrolytic refining of zinc, anode is made up of impure zinc while a strip of pure zinc acts as cathode. An acidified solution of zinc sulphate acts as electrolyte. When electricity is passed, following reactions occur.

At cathode $$ Zn ^{2+}+2 e ^{-} \rightarrow \underset{\text { (pure) }}{ Zn } $$ At anode $$ \underset{\text { (impure) }}{ Zn } \rightarrow Zn ^{2+}+2 e ^{-} $$