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Chemistry
In the diazotization of aryl amines with sodium nitrite and hydrochloric acid, an excess of hydrochloric acid is used primarily to
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Q. In the diazotization of aryl amines with sodium nitrite and hydrochloric acid, an excess of hydrochloric acid is used primarily to
Punjab PMET
Punjab PMET 1998
Amines
A
suppress the concentration of free aniline available for coupling
38%
B
suppress hydrolysis of phenol
21%
C
ensure a stoichiometric amount of nitrous acid
22%
D
neutralise the base liberated
20%
Solution:
Excess of hydrochloric acid avoids the possibility of coupling reaction by leaving no free aniline for coupling reaction.