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Chemistry
In the change of NO → NO+ the electron is added to
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Q. In the change of $NO \, \to\, NO^+$ the electron is added to
Delhi UMET/DPMT
Delhi UMET/DPMT 2009
Chemical Bonding and Molecular Structure
A
$\sigma$ - orbital
13%
B
$\pi$ - orbital
26%
C
$\sigma^*$ - orbital
26%
D
$\pi^*$ - orbital
35%
Solution:
M.O. configuration of $NO ^{+}$is
$\sigma 1 s^{2}, \sigma^{*} 1 s^{2}, \sigma 2 s^{2}, \sigma^{*} 2 s^{2}, \pi 2 p_{x}^{2} \approx \pi 2 p_{y}^{2}, \pi 2 p_{z}^{2}$
and M.O. configuration of $NO$ is
$\sigma 1 s^{2}, \sigma^{*} 1 s^{2}, \sigma 2 s^{2}, \sigma^{*} 2 s^{2}, \pi 2 p_{x}^{2} \approx \pi 2 p_{y}^{2}, \pi^{*} 2 p_{x}^{1}$