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Chemistry
In FCC unit cell, what fraction of edge is not covered by atoms?
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Q. In $FCC$ unit cell, what fraction of edge is not covered by atoms?
The Solid State
A
0.134
B
0.293
C
0.26
D
0.32
Solution:
$\frac{ h }{ a }=$ fraction of edge not covered by atoms
$2 r+n=a$
$ n=a-2 r$
$\frac{a-2 r}{a}=$ fraction of edge not covered
$2 r=\frac{\sqrt{2 a}}{2}$
$r=\frac{\sqrt{2 a}}{4}=\frac{a}{2 \sqrt{2}}$
$\frac{a-2 \times \frac{a}{2 \sqrt{2}}}{a}=$ fraction of edge not covered
$\frac{ a \left(1-\frac{1}{\sqrt{2}}\right)}{ a }=$ fraction of edge not covered
$\frac{\sqrt{2}-1}{\sqrt{2}}=\frac{1.414-1}{1.414}$
$=\frac{0.414}{1.414} =0.293=$ fraction of edge not covered