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  4. In a group of isomeric alkyl halides, the order of boiling points is

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Q. In a group of isomeric alkyl halides, the order of boiling points is

J & K CETJ & K CET 2007Haloalkanes and Haloarenes

Solution:

Alkyl halides with branched and more spherical shapes have lower boiling point as a result of their smaller surface area. So, order of boiling points is Primary > secondary > tertiary