Relationship between $\Psi_w, \Psi_s$ and $\Psi_p$ in a 28 typical vacuolated cell is as follows :
$\Psi_w = \Psi_s + \Psi_p$
At zero turgor, $\Psi_p = 0$, then $\Psi_s = \Psi_w$ยท
In fully turgid cell, $\Psi_p$ and $\Psi_s$ are equal, but
with opposite signs, hence $\Psi_w$ = 0.
Mature cells show intermediate state between zero turgor and full turgor.