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  4. In a benzene ring substitution with - NH 2 group, orientation is controlled by

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Q. In a benzene ring substitution with $- NH _{2}$ group, orientation is controlled by

Organic Chemistry – Some Basic Principles and Techniques

Solution:

$- NH _{2}$ group shows both $-I$ and $+M$ effect but resonance effect $(+M)$ dominates inductive effect $(-I)$