As we know, according to Brewster's law, refractive index,
$\mu=\tan \theta_p \text {.(i) }$
where, $\theta_p$ is polarising angle. Critical angle,
$\sin \theta_c=\frac{1}{\mu}$
Or $\mu=\frac{1}{\sin \theta_c} \ldots$(ii)
From Eqs. (i) and (ii), we get
$\frac{1}{\sin \theta_c}=\tan \theta_p$
or $\tan \theta_p \sin \theta_c=1$