If the principle quantum number $n=6$, the correct sequence of filling of electron will be $ns \rightarrow( n - 2 ) f \rightarrow( n - 1 ) d \rightarrow np$
Here, $n =6$. Hence, the correct sequence of filling of electron will be $6 s \rightarrow 4 f \rightarrow 5 d \rightarrow 6 p$.