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Q. If on transition to the ground state an $He^{+}$ ion emits two photons in succession, having wavelengths $1026.7\overset{^\circ }{A}$ and $304\overset{^\circ }{A}$ , then the quantum number $n$ corresponding to the exciting state of $He^{+}$ ion is [ $R=1.096\times 10^{7}m^{- 1}$ ]

NTA AbhyasNTA Abhyas 2020Atoms

Solution:

$\frac{h c}{\lambda_1}+\frac{h c}{\lambda_2}=\operatorname{Rch} Z^2\left(\frac{1}{1^2}-\frac{1}{n^2}\right)$
Put $\lambda _{1}=1026.7Å$ and $\lambda _{2}=304 \, Å$
$Z=2$ for $He^{+}$ ion
On solving for $n$
$n=6$