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Chemistry
If λ =c2[(n2/n2 - 22)] for Balmer series, what is the value of c2 ?
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Q. If $\lambda =c_{2}\left[\frac{n^{2}}{n^{2} - 2^{2}}\right]$ for Balmer series, what is the value of $c_{2}$ ?
NTA Abhyas
NTA Abhyas 2020
Structure of Atom
A
$\frac{4}{R_{H}}$
16%
B
$\frac{2}{R_{H}}$
36%
C
$2R_{H}$
32%
D
$4R_{H}$
16%
Solution:
$\lambda =c_{2}\left[\frac{n^{2}}{n^{2} - 2^{2}}\right]$
or $\frac{1}{\lambda }=\frac{1}{c_{2}}\left[\frac{n^{2} - 2^{2}}{n^{2}}\right]=\frac{1}{c_{2}}\left[1 - \frac{2^{2}}{n^{2}}\right]$
$=\frac{2^{2}}{c_{2}}\left[\frac{1}{2^{2}} - \frac{1}{n^{2}}\right]$
So, $R_{H}=\frac{2^{2}}{c_{2}}$ or $c_{2}=\frac{4}{R_{H}}$