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Chemistry
Identify the set of paramagnetic ions among the following:
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Q. Identify the set of paramagnetic ions among the following:
KCET
KCET 2020
The d-and f-Block Elements
A
$V^{2+}, Co^{2+} , Ti^{4+}$
11%
B
$Ni^{2+}, Cu^{2+} , Zn^{2+}$
14%
C
$Ti^{3+}, Cu^{2+} , Mn^{3+}$
63%
D
$Sc^{3+}, Ti^{3+} , V^{3+}$
13%
Solution:
The ions which contain unpaired electrons exhibit paramagnetic behaviour.
The electronic configuration of the ions are given below:
$Ti ^{3+}=1 s ^{2} 2 s ^{2} 2 p ^{6} 3 s ^{2} 3 p ^{5}$
$Cu ^{2+}=1 s ^{2} 2 s ^{2} 2 p ^{6} 3 s ^{2} 3 p ^{5} 3 d ^{9}$
$Mn ^{3+}=1 s ^{2} 2 s ^{2} 2 p ^{6} 3 s ^{2} 3 p ^{5} 3 d ^{4}$
Thus, all of them have unpaired electrons. Hence, they will show paramagnetic behaviour.
In option (B) $V ^{3+}$ does not possess any unpaired electrons.
In option (C) $Zn ^{2+}$ does not possess any unpaired electrons.
Similarly, in option (D) $Zn ^{2+}$ does not possess any unpaired electrons.