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Chemistry
HX is a weak acid ( Ka = 10 - 5 ).lt forms a salt NaX (0.1 M) on reacting with caustic soda. The degree of hydrolysis of Na X is
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Q. $HX$ is a weak acid ( $ K_a = 10^{ - 5} $ ).lt forms a salt $NaX (0.1\,M)$ on reacting with caustic soda. The degree of hydrolysis of $Na X $ is
IIT JEE
IIT JEE 2004
Equilibrium
A
0.01 %
50%
B
0.0001%
18%
C
0.1%
14%
D
0.5%
18%
Solution:
$ K_h \, ( X^ - ) = \frac{ K_w }{ K_a } = \frac{ 10^{ - 1 4 }}{ 10^{ - 5 }} = 10^{ - 9 } $
$ \alpha = \sqrt{ \frac{ K_h }{ C } } = \sqrt{ \frac{ 10^{ - 9 } }{ 0.10 } } = 10^{ - 4 } $
$\%$ hydrolysis $= 100 \alpha =0.01$