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Q. How many of the following are the CORRECT expressions to calculate e.m.f. of the cell?
i. $ E_{\text {cell }}=E_{\text {oxi }}$ (anode) $+E_{\text {red }}$ (cathode)
ii. $E_{\text {cell }}=E_{\text {red }}$ (anode) $-E_{\text {red }}$ (cathode)
iii. $E_{\text {cell }}=E_{\text {oxi }}$ (anode) $-E_{\text {oxi }}$ (cathode)
iv. $E_{\text {cell }}=E_{\text {red }}$ (cathode) $-E_{\text {red }}$ (anode)
v. $E_{\text {cell }}=E_{\text {red }}$ (cathode) $+E_{\text {red }}$ (anode)
vi. $E_{\text {cell }}=E_{\text {oxi }}$ (anode) $+E_{\text {oxi }}$ (cathode)

Electrochemistry

Solution:

Expressions $(i), (iii)$ and $(iv)$ are the correct expressions to calculate e.m.f. of the cell.