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Q. How many of the following alkyl halides will readily undergo $S_{N}1$ reaction mechanism?
Question

NTA AbhyasNTA Abhyas 2022

Solution:

Only benzylic halides $1^{\circ}, 2^{\circ}, 3^{\circ}$, allylic halides $1^{\circ} .2^{\circ}, 3^{\circ}$ and tertiary alkyl halides undergo $S _{ N } 1$ mechanism most readily. Benzylic halides: $(I), (VI) $Allylic halides: $(II), (I V)$ Tertiary alkyl halide: $(VIII)$