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Chemistry
H 3 PO 4( d =1.8 g / mL ) is 18 M. Hence, mass percentage and molality are:
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Q. $H _{3} PO _{4}( d =1.8\, g\, / mL )$ is $18 \,M$. Hence, mass percentage and molality are:
Some Basic Concepts of Chemistry
A
18,32.4
33%
B
98,32.4
24%
C
98,500
14%
D
98,18
29%
Solution:
Density $=1.8 \,g /\, mL$
Molarity $=18 \,M =18\, mol \,H _{3} PO _{4}$ in $1\, L$ solution
$1000 \,mL$ solution has $H _{3} PO _{4}=18 \,mol =18 \times 98 \,g$
$100 \,mL =(1800 \,g )$ solution has $H _{3} PO _{4}=18 \times 98\, g$
$H _{3} PO _{4}$ by mass $\%$ (by weight of solution)
$=\frac{18 \times 98}{1800} \times 100=98 \%$
or $(1800-18 \times 98) \,g\, H _{2} O$ (solvent) $H _{3} PO _{4}=18 \times 98\, g$
$2\, g$ solvent has $H _{3} PO _{4}=98\, g =1 \,mol \,H _{3} PO _{4}$
$1 \,g =1000 \,g$ solvent has $H _{3} PO _{4}=500$ molal
Thus, $98 \%, 500$ molal