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Q. Given that 1g of water in liquid phase has volume 1cm3 and in vapour phase 1671cm3 at atmospheric pressure and the latent heat of vaporization of water is 2256J/g; the change in the internal energy in joules for 1g of water at 373K when it changes from liquid phase to vapour phase at the same temperature is:

JEE MainJEE Main 2013Thermal Properties of Matter

Solution:

ΔQ=ΔU+ΔW2256=ΔU+P0ΔV=ΔU+105(1670×106)
ΔU=2089J