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Q. Given below are two statements:
Statement I : A mixture of chloroform and aniline can be separated by simple distillation
Statement II : When separating aniline from a mixture of aniline and water by steam distillation aniline boils below its boiling point. In the light of the above statements, choose the most appropriate answer from the options given below

JEE MainJEE Main 2021Organic Chemistry – Some Basic Principles and Techniques

Solution:

Statement 1: $B.P$. of chloroform $=334 \,K$

$B.P$. of aniline $=457\, K$

thus can be seprated of simple distillation.

Statement 2 : Mixture of aniline and water seprated by simple distillation.