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Q.
Formula Moles of AgCl precipitated per mole of the compounds with excess $AgNO N _{3}$
I $PdCl _{2} \cdot 4 NH _{3}$ $2$
II $NiCl _{2} \cdot 6 H _{2} O$ $2$
III $PtCl _{4} \cdot 2 HCl$ $0$
IV $CoCl _{3} \cdot 4 NH _{3}$ $1$
V $PtCl_2 \cdot 2 NH _{3}$ $0$

The secondary valencies of I and III is

Coordination Compounds

Solution:

Secondary valency means coordination number. So, the secondary valencies of $I$ and $III$ are $4$ and $6$ respectively.