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Q. For the reaction, $ PCl_5 \, ( g) \rightleftharpoons PCl_3 \, ( g) + Cl_2 \, ( g) $ the forward reaction at constant temperature is favoured by

IIT JEEIIT JEE 1991Equilibrium

Solution:

If inert gas is introduced at constant pressure, volume of container will have to be increased and this will favour the forward reaction. Also adding $PCl_5$ (g )at constant volume will favour forward reaction because $PCl_5$ (g ) is a reactant.