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Q. For the reaction $C _2 H _5 OH ( l )+3 O _2( g ) \longrightarrow 2 CO _2( g )+3 H _2 O ( l )$ which one is true:

AIPMTAIPMT 2000Thermodynamics

Solution:

We know that $\Delta H=\Delta E+\Delta nRT$
where $\Delta n$ = number of moles of gaseous product - number of moles of gaseous reactant
$= 2 - 3 = - 1$
So, $\Delta H=\Delta E-RT$