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Q. For extraction of sodium from $NaCl$, the electrolytic mixture $NaCl + Na_{3}AlF_{6} + CaCl_{2}$ is used. During extraction process, only sodium is deposited on cathode but K and Ca do not because

General Principles and Processes of Isolation of Elements

Solution:

As $K$ and $Ca$ are more reactive than $Na$ & they have less discharge potential than Na so they will not discharge