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Q. Enthalpy change for the reaction,
$4 H _{( g )} \rightarrow 2 H _{2( g )}$ is $-869.6\, kJ$
The dissociation energy of $H - H$ bond is

AIPMTAIPMT 2011Thermodynamics

Solution:

Given
$4H(g) \to 2H_{2}(g) ; \Delta H = - -869.6 \, kJ$
or $2H_{2} (g) \to 4H(g) ; \Delta H = 869.6\, kJ$
$H_{2} (g) \to 2H(g) ; \Delta H = \frac{869.6}{2} = 434.8\, kJ$