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Q. Effective atomic number (EAN) of $\text{Mn}$ in $\left[\mathrm{Mn}_2(\mathrm{CO})_{10}\right]$ is

NTA AbhyasNTA Abhyas 2020Coordination Compounds

Solution:

In $\left[\mathrm{Mn}_2(\mathrm{CO})_{10}\right]$, there is one $\mathrm{Mn}-\mathrm{Mn}$ bond

Electron present in 2 Mn = 50

Electrons donated by 10 CO = 20

Electrons in one $\text{Mn} - \text{Mn}$ bond = 2

Total electrons = 72

So EAN per $Mn=\frac{72}{2}=36$ .