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Q. Decomposition of A follows first order kinetics by the following equation.
$4 A ( g ) \longrightarrow B ( g )+2 C ( g )$
If initially, total pressure was $800\, mm$ of $Hg$ and after $10$ minutes it is found to be $650\, mm$ of $Hg$. What is half-life (in $ \min$.) of $A$ ? (Assume only $A$ is present initially)

Chemical Kinetics

Solution:

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$\therefore p=150$
Pressure of $A=200$, so
$\therefore 2 \times t_{1 / 2}=10$ minutes
$t_{1 / 2}=5$ minutes